Evaluating the Environmental Sustainability of Alternative Ways to Produce Benzene, Toluene, and Xylene.

The petrochemical industry can reduce its environmental impacts by moving from fossil resources to alternative carbon feedstocks. Biomass and plastic waste-based production pathways have recently been developed for benzene, toluene, and xylene (BTX). This study evaluates the environmental impacts of these novel BTX pathways at a commercial and future (2050) scale, combining traditional life cycle assessment with absolute environmental sustainability assessment using the planetary boundary concept. We show that plastic waste-based BTX has lower environmental impacts than fossil BTX, including a 12% decrease in greenhouse gas (GHG) emissions. Biomass-based BTX shows greater GHG emission reductions (42%), but it causes increased freshwater consumption and eutrophication. Toward 2050, GHG emission reductions become 75 and 107% for plastic waste and biobased production, respectively, compared to current fossil-BTX production. When comparing alternative uses of plastic waste, BTX production has larger climate benefits than waste incineration with energy recovery with a GHG benefit of 1.1 kg CO2-equiv/kg plastic waste. For biomass (glycerol)-based BTX production, other uses of glycerol are favorable over BTX production. While alternative BTX production pathways can decrease environmental impacts, they still transgress multiple planetary boundaries. Further impact reduction efforts are thus required, such as using other types of (waste) biomass, increasing carbon recycling, and abatement of end-of-life emissions.

Life cycle thinking for the assessment of waste and circular economy policy: status and perspectives from the EU example.

Life cycle thinking methods such as life cycle assessment (LCA) and costing (LCC) were originally developed to assess the performance of products and services (business-making decisions). However, they are increasingly deployed to support policy-making along the entire policy cycle, including via impact assessment (IA) of different policy options. These applications are associated with a number of challenges, mainly related to the dynamic and prospective nature of policy IA, typically forward-looking into 10-20 years ahead. This requires the application of prospective scenario analyses to develop the baseline scenario, reflecting the 'do nothing' into the future (business-as-usual), and the alternative scenarios, reflecting the consequences incurred by the implementation of the policy options under study. Such prospective and broadened boundary nature of policy IA challenges traditional LCA/LCC practices mostly based on retrospective, static scenarios and datasets. The present study provides an overview of recent IA studies supporting waste policy to show the state-of-the-art and the main challenges associated with the application of life cycle methods in IA, focusing on the most recent EU waste and circular economy policies. Moreover, since specific and transparent guidance on how to implement consistently these methods in policy IA is lacking, the study provides an initial guidance for application of life cycle thinking in IA drawing upon the knowledge obtained conducting waste policy IA studies. Key challenges in the field are still to be addressed, and might inspire further research to improve the application of life cycle thinking to policy assessment.

Multiple criteria decision analysis to support the design of safe and sustainable chemicals and materials.

The development of safe and sustainable chemicals and materials is essential to achieve the Zero-Pollution Ambition for a Toxic Free Environment stated in the EU Green Deal. For that, criteria need to be defined and considered since early stage of development. A Safe and Sustainable by Design (SSbD) framework is proposed in an EU Recommendation suggesting the assessment of multiple safety and sustainability aspects of chemicals and materials leaving open how the evaluation and selection of the preferable option should be done. This paper presents a proposal with different options for the use of multiattribute aggregation in an evaluation procedure for the SSbD assessment of chemicals and materials. This proposal is based on i) a review of the literature focusing on Multi-Criteria Decision Analysis (MCDA) application in the SSbD context (i.e. applications considering simultaneously safety and sustainability attributes) and ii) the definition of requisites for MCDA to be applied to the SSBD framework. In the latter, an absolute rather than a relative assessment is preferred as it should be possible for an organization developing a new chemical or material to assess if it is SSbD, without needing to obtain data on all of its possible competitors. Moreover, rank-reversals caused by the introduction of other options are avoided, i.e., assessments of one alternative that depends on other alternatives being assessed simultaneously are not the most adequate. Different options for the aggregation of attributes at different levels are discussed as well as for the consideration of data quality in the evaluation procedure. Regardless the approach selected, the use of multiattribute aggregation does not rule out a richer dashboard presenting not only the overall aggregate result, but also the results obtained in other levels of the hierarchy. Such complementary information is important to understand the strengths and weaknesses that an aggregate result might hide.

The potential of emerging bio-based products to reduce environmental impacts.

The current debate on the sustainability of bio-based products questions the environmental benefits of replacing fossil- by bio-resources. Here, we analyze the environmental trade-offs of 98 emerging bio-based materials compared to their fossil counterparts, reported in 130 studies. Although greenhouse gas life cycle emissions for emerging bio-based products are on average 45% lower (-52 to -37%; 95% confidence interval), we found a large variation between individual bio-based products with none of them reaching net-zero emissions. Grouped in product categories, reductions in greenhouse gas emissions ranged from 19% (-52 to 35%) for bioadhesives to 73% (-84 to -54%) for biorefinery products. In terms of other environmental impacts, we found evidence for an increase in eutrophication (369%; 163 to 737%), indicating that environmental trade-offs should not be overlooked. Our findings imply that the environmental sustainability of bio-based products should be evaluated on an individual product basis and that more radical product developments are required to reach climate-neutral targets.

Grown and thrown: Exploring approaches to estimate food waste in EU countries.

National studies on food waste quantification in EU countries present highly discrepant results due to the different quantification approaches adopted. The European Commission has published a delegated act establishing a common methodology and minimum quality requirements for the uniform measurement of food waste generated in Member States. Nevertheless, as EU countries are at different levels of development and implementation of national strategies for food waste quantification, there is a need to develop a harmonized modelling system that enables the estimation of food waste generated by Member States to assess the amounts reported by each country. The aim of this paper is to fulfil this need by presenting two modelling approaches to estimate food waste in EU countries. One approach is based on Material Flow Analysis (MFA) and combines statistical information on the production and trade of food products with food waste coefficients. The other approach is based on the estimation of food waste based on waste statistics. Three EU countries are used to illustrate the two approaches and compare the results obtained thereby. Food waste estimates from waste statistics are generally lower than those obtained using MFA, in particular at the early stages of the food chain. The MFA model presented in this article is the first of its kind developed to estimate food waste across Member States in a consistent way and through time. Crucially, this could support the definition of a baseline and binding targets to reduce food waste across the EU, as announced in the EU Farm to Fork Strategy.

No time to waste: assessing the performance of food waste prevention actions.

As a result of the growing awareness of the need to prevent food waste, several initiatives have been launched in the last few years to reduce food waste generated across the food supply chain. However, the evaluation of food waste prevention interventions is still at an early stage of development and appropriate methods to assess their effectiveness are missing, hampering the identification of best practices amongst existing initiatives and the prioritisation of those that are most promising. To address such needs and provide a common approach to consistently assess the performance of food waste prevention initiatives, the European Commission Joint Research Centre has developed an evaluation framework for food waste prevention actions. The framework supports the EU Platform on Food Losses and Food Waste, which has been established to identify best practices and share knowledge on food waste prevention initiatives. Additionally, a food waste prevention calculator, based on life cycle thinking, has been developed to support such an evaluation by a consistent assessment of the environmental and economic benefits of such initiatives, and the identification of potential trade-offs at early design stages. The main goal of this paper is to present the evaluation framework and the calculator developed, critically discussing how future initiatives should be designed, monitored and reported, to ensure sufficient and relevant data is made available to enable their proper assessment. Crucially, this would enable practitioners and decision makers to evaluate the success of existing initiatives and give priority to the implementation of the best performing ones.

Sustainability of food waste biorefinery: A review on valorisation pathways, techno-economic constraints, and environmental assessment.

The need to increase circularity of industrial systems to address limited resources availability and climate change has triggered the development of the food waste biorefinery concept. However, for the development of future sustainable industrial processes focused on the valorisation of food waste, critical aspects such as (i) the technical feasibility of the processes at industrial scale, (ii) the analysis of their techno-economic potential, including available quantities of waste, and (iii) a life cycle-based environmental assessment of benefits and burdens need to be considered. The goal of this review is to provide an overview of food waste valorisation pathways and to analyse to which extent these aspects have been considered in the literature. Although a plethora of food waste valorisation pathways exist, they are mainly developed at lab-scale. Further research is necessary to assess upscaled performance, feedstock security, and economic and environmental assessment of food waste valorisation processes.

Unveiling the potential for an efficient use of nitrogen along the food supply and consumption chain.

Ensuring global food security is one of the challenges of our society. Nitrogen availability is key for food production, while contributing to different environmental impacts. This paper aims firstly to assess nitrogen flows and to highlight hotspots of inefficient use of nitrogen along the European food chain, excluding primary production. Secondly, it aims to analyse the potential for reducing the identified inefficiencies and increase nitrogen circularity. A baseline and three scenarios-reflecting waste targets reported in EU legislation and technological improvements- are analysed. Results highlighted a potential to reduce reactive nitrogen emissions up to more than 45%. However, this would imply the conversion of reactive nitrogen in molecular nitrogen, such as urea, before re-entering in the food chain. Techniques to harvest reactive nitrogen directly from urine and wastewater are considered promising to increase nitrogen use efficiency along the food chain.

Quantification of food waste per product group along the food supply chain in the European Union: a mass flow analysis.

In 2015, the United Nations defined the Sustainable Development Goals (SDG), which include a target (12.3) on food waste. The target requires "by 2030, to halve per capita global food waste at the retail and consumer levels and to reduce food losses along production and supply chains, including post-harvest losses". The target has increased awareness about the food waste problem and boosted research in food waste quantification. Nevertheless, there is a lack of studies that adopt a systematic approach to account for food waste providing disaggregated values per food supply chain stage and per food groups. Such an approach could support policy makers in prioritizing interventions for food waste reduction. To fill this gap, this paper presents a high-level top-down approach to food waste accounting in the European Union. The study aims to support the understanding of the mass flows associated with food production, consumption, and waste, addressing different food groups along the food supply chain. The method for accountin is the mass flow analysis. According to the results, cereals, fruit, and vegetables as the food groups are responsible for the highest amount of food waste, and the consumption stage to be responsible for the largest share of food waste for most food groups. This work highlights the need for further primary research on food waste generation in the EU. Ultimately, this would allow to robustly estimate the food waste generated at EU level, and establishing a more accurate baseline to track the progress towards SDG target 12.3.

Food waste accounting methodologies: Challenges, opportunities, and further advancements.

About one third of the food produced globally is wasted along the food chain, representing a burden for the environment and an inefficiency of the food system. Tackling food waste is a priority on the global political agenda to guarantee food security. Defining a methodology for food waste quantification is key to monitoring progress towards the achievement of reduction targets. This paper summarises the outcomes of a workshop on food waste accounting co-organised by the European Commission's Joint Research Centre and Directorate-General on Health and Food Safety with the aim of stimulating harmonisation of methodologies, identifying challenges, opportunities, and further advancement for food waste accounting. The paper presents methodological aspects, e.g. system boundaries, reliability of data, accounting of water flows, to ensure better support to food waste policy design and interventions. It addresses all the actors of the food supply chain, governments, and research institutions.

Techno-economic and profitability analysis of food waste biorefineries at European level.

Food waste represents a potential source to produce value-added materials replacing the use of virgin ones. However, the use of food waste as feedstock in biorefineries is still at an early stage of development and studies assessing its economic viability at large scale are lacking in the literature. This paper presents a techno-economic and profitability analysis of four food waste biorefineries that use wastes from tomato, potato, orange, and olive processing as feedstock. The study includes the assessment of potentially available quantities of those waste flows in Europe. Due to the low technology readiness level of this kind of biorefineries, a screening methodology to estimate the investment and manufacturing costs as well as two profitability ratios (the return on investment and the payback time) was adopted. Results show that not all the waste feedstocks have the same potential. The most profitable options are those related to implementing fewer plants, namely concentrating the production and capitalising on economies of scale while being at risk of increasing externalities, e.g. due to logistics of the feedstocks.

Qualidade de sementes de tabaco durante o processo de pelotização e armazenamento / Quality of tobacco seeds during the pelletizing process and storage

RESUMO: O processo de pelotização pode afetar a qualidade das sementes por ocasião da semeadura, por isso, para avaliar o efeito desse processo na qualidade das sementes, foram utilizadas sementes de duas cultivares de tabaco 'CSC 467' e 'CSC 07', coletadas em diferentes etapas do processo de beneficiamento e pelotização: 1) sementes nuas não beneficiadas; 2) sementes nuas beneficiadas; 3) sementes pelotizadas; 4) sementes pelotizadas e coloridas. Para avaliação da qualidade das sementes nessas diferentes etapas, foram realizados os seguintes testes: germinação, primeira contagem de germinação, índice de velocidade de germinação, teste de emergência e índice de velocidade de emergência. Posteriormente, as sementes foram armazenadas por seis e doze meses e sua qualidade avaliada pelos mesmos testes e determinações. O processo de pelotização avaliado não influencia na germinação final de sementes de tabaco, mas atrasa o processo germinativo. As sementes de tabaco das cultivares 'CSC 467' e 'CSC 07' mantêm sua qualidade durante os 12 meses de armazenamento em câmara fria, com temperatura de 10°C e umidade relativa de 50%.

ABSTRACT: The pelletizing process may affect the quality of seeds during sowing. In order to evaluate the effect of this process on seed quality it was used seeds from three tobacco cultivars, 'CSC 467' and 'CSC 07' collected in different processing and pelletizing process stages: 1) non processed nude seeds; 2) processed nude seeds; 3) pelletized seeds; 4) pelletized and colored seeds. For the evaluation of seed quality in these different stages it was performed the following tests: Germination, First Count of Germination, Germination Speed Index, Initial and Final Stand (Emergence) and Emergence Speed Index. Posteriorly, seeds were stored for six and twelve months and their quality was evaluated by the same tests and determinations. The evaluated pelletizing process does not influence final germination of the tobacco seeds, but delays the germination process. Tobacco seeds from cultivars 'CSC 467' and 'CSC 07' maintain their quality during the 12 months of storage in cold chamber with temperature of 10oC and relative humidity of 50%.